Photophysical Properties and Photosubstitution and Photoredox Reactions of Aromatic Nitro Compounds

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Photosubstitution Reactions of Aromatic Compounds

In nucleophilic aromatic photosubstitution, just as in aromatic substitution in the ground state, substituents can have directing and activating effects. Four rules, which describe orientation of nucleophilic substitution in the excited state, can now be formulated. They are: (a) meta-activation by the nitro group (b) ortho/para-activation by the methoxy group (and probably also by other electr...

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A reaction from various kinds of nitroquinoline with hydroxylamine in potassium hydroxide alkalinity produced a novel product, furazanoquinoline, besides the known amino derivatives. The products obtained were furazano [3,4-f] quinoline (5) from 5-nitroquinoline (1) and 6-nitroquinoline (6), and furazano [3,4-h] quinoline (10) from 7-nitroquinoline (8) and 8-nitroquinoline (11). The reaction me...

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ژورنال

عنوان ژورنال: Bulletin of the Chemical Society of Japan

سال: 1996

ISSN: 0009-2673,1348-0634

DOI: 10.1246/bcsj.69.261